The digital divide in developing economies persists as a multidimensional challenge encompassing infrastructure access, digital skills, usage patterns, and social inequality. This paper presents a structured literature review of 63 peer-reviewed articles (2018–2025) examining how intelligent connectivity, the convergence of fifth-generation (5G) mobile networks, artificial intelligence (AI), and the Internet of Things (IoT), can contribute to bridging this divide. The findings reveal that intelligent connectivity offers transformative potential across agriculture, healthcare, education, and financial services. However, its impact is contingent upon enabling governance, institutional capacity, and digital skills. Three contributions emerge: (1) a conceptual framework specifying directional pathways from enabling conditions to intelligent connectivity deployment and inclusive outcomes; (2) a comparative regional analysis (Sub-Saharan Africa, Southeast Asia, and Latin America) identifying context-specific barriers and opportunities; and (3) a socio-technical model positioning intelligent connectivity as an integrated system rather than a purely technological solution. A key limitation is acknowledged: only 16% of the reviewed corpus addresses developing economies, necessitating triangulation with institutional reports from the International Telecommunication Union (ITU), Organization for Economic Co-operation and Development (OECD), and Global System for Mobile Communications Association (GSMA). The paper concludes with open research challenges and policy recommendations for inclusive digital transformation.