Studies have established that extreme air pollution is more prevalent and is responsible for more deaths and disability-adjusted life years (DALY) in urban cities, especially in developing economies. However, the paucity of ground-based observation has greatly hindered extensive and long-term monitoring and, as such, a good understanding of the trend and characteristics of air quality where it matters most. Aerosol optical depth (AOD) from satellites retrievals provides good spatial and temporal resolutions of atmospheric aerosols and could be a good proxy for ground-level PM2.5 concentration. This study used a Bayesian regression model to determine the parameters of a PM2.5 model at four monitoring stations using AOD and selected atmospheric variables (PBLH and RH) as input. The dry-air reference value (K) and the integrated humidity coefficient (γ) were used to delineate the effects of the aerosol characteristics. The values of K and γ, 0.02