As part of improving the performance of active stills, we numerically studied the effects of sunlight on a concentrating still. This is a double-slope solar still under which a parabolic trough concentrator was placed. We were particularly interested in the impact of sky conditions on productivity, overall and internal efficiency, and exergy efficiency. Applying the energy balance method to the different components of the still allowed us to calculate the productivity and the various efficiencies of the system. Our system was simulated for the climatic conditions of the city of Ouagadougou (located at 12.35 North latitude and 1.32 West) and for April. These results show that the nature of the sky has a significant impact on the operating characteristics of the still. Indeed, the productivity, the overall, internal, and exergy efficiency of the distiller are a function of the sunshine and therefore depend on the nature of the sky. These characteristics improve with the increase in sunshine. The best operating characteristics are obtained for a clear sky because the sunshine is higher. We have a maximum overall radiation of 936.504 W/m² for a clear sky against 866.24 W/m² and 755.69 W/m² for a sky with normal atmospheric conditions and a polluted sky. For a clear sky, we obtained a maximum productivity of 0.0014 kg/'s against 0.0011 kg/s and 0.0007 kg/s for a sky with normal atmospheric conditions and for a polluted sky. It was concluded that productivity, the different efficiencies are strongly affected by sunshine. The higher the radiation intensity, the better the productivity of the distiller.