NOAA/WDS Paleoclimatology - Isotope data for Sale Briqueterie section, Morocco

We report a high-resolution stable isotope, carbonate, magnetostratigraphic, and biostratigraphic record from a 175-m drill core from the Salé Briqueterie, which is part of the Bou Regreg section in northwestern Morocco. The Salé drill core spans the interval from paleomagnetic Chron C4n partim to C3r (earliest Gilbert), which represents the time leading up to and including the isolation and desiccation of the Mediterranean (i.e., the Messinian salinity crisis). During Chrons C3An and C3Ar (6.935 to 5.894 Ma) the isotope and carbonate signals display quasi-periodic variations with estimated periods of 40 and 100 kyr, respectively. We interpret the 40-kyr δ18O variations as reflecting changes in global ice volume caused by obliquity-induced changes (41 kyr) in solar insolation in polar regions. The 100-kyr carbonate variations probably represent long-term modulation of the amplitude of the precessional cycle (∼21 kyr), which is not resolved by our sampling frequency. The cyclic nature of the oxygen isotope signal permits us to extend the isotope nomenclature of Shackleton et al. (1994a) from stage TG24 in Chron C3r (earliest Gilbert) to stage C3Ar.δ18O.18 at the base of Chron C3Ar (6.935 Ma). A major change in paleoceanographic conditions is recorded across the Tortonian/Messinian boundary, which we correlate to Chron C3Bn at 7.04 Ma. Benthic foraminiferal δ18O values increased by an average of 0.4‰ in two steps at 7.17 Ma and 6.8 Ma and δ13C values decreased by 0.7–0.8‰ between 7.1 and 6.8 Ma, representing the late Miocene carbon shift. The first step in δ18O values coincides with an inferred reversal in deep water circulation through the Rifian Corridor, and the second correlates with the base of the Tripoli Formation and onset of “crisis conditions” in the Mediterranean. We suggest that the increase in δ18O values represents, at least in part, an increase in global ice volume that lowered sea level and contributed to the establishment of a negative water budget in the Mediterranean. Average δ18O values remained high throughout most of Chrons C3Ar and C3An, reaching maximum δ18O values during isotope stages TG20 and 22 in Chron C3r (earliest Gilbert). The glacio-eustatic falls associated with these events may have resulted in the complete isolation of the Mediterranean from the world ocean (Shackleton et al., 1994a). Following stage TG12 in the Salé record, there exists a trend toward progressively lower δ18O values that may represent a series of marine transgressions that eventually reflooded the Mediterranean and ended the Salinity Crisis.