This dataset contains derived geospatial products generated from Landsat imagery to support analysis of urban expansion and associated ecosystem service value (ESV) decline in the Sekondi Takoradi Metropolis, Ghana, for the period 1991–2023. The dataset includes classified land use land cover (LULC) raster maps for the study years (1991, 2009, 2016, and 2023), along with supporting layers and tabular outputs used to quantify LULC transitions and ESV change over time. LULC classes follow the categories reported in the associated publication.